Mg-Al系镁合金的糖心产精国品免费入口*完整版能研究进展
Research Progress on Corrosion Resistance of Mg-Al Magnesium Alloy
摘 要
镁合金作为绿色轻质结构材料被广泛应用于工业生产，但糖心产精国品免费入口*完整版较差制约着其发展。与其他系列镁合金相比，Mg-Al系镁合金具有更优异的糖心产精国品免费入口*完整版。着重介绍了Mg-Al二元合金的腐蚀特点、机理。分析了第三项合金元素对α相自腐蚀电位，第二相析出相的种类、数量、分布，杂质元素（Fe/Cu/Ni）容许极限的影响。糖心产精国品免费入口*完整版和热变形工艺（如：糖心产精国品免费入口*完整版、热挤压）对微观组织结构的影响，并讨论了相应的腐蚀特性变化。概述了Mg-Al系合金常用表面处理技术及防护效果。
糖心产精国品免费入口*完整版
糖心产精国品免费入口*完整版
糖心产精国品免费入口*完整版
糖心产精国品免费入口*完整版
表面处理
Mg-Al alloy
糖心产精国品免费入口*完整版
糖心产精国品免费入口*完整版
糖心产精国品免费入口*完整版
糖心产精国品免费入口*完整版
surface treatment
Abstract
Magnesium alloys as a green light structural materials are widely used in industry. However, the poor 糖心产精国品免费入口*完整版 is a challenge which limits their wider application. Mg-Al series alloys exhibit better corrosion properties, as compared with other Mg alloys. The corrosion characteristics and mechanism of Mg-Al binary alloy are introduced. The influence of alloying elements on the corrosion performance is analyzed. The effects of 糖心产精国品免费入口*完整版 and deformation, especially 糖心产精国品免费入口*完整版 and extrusion deformation on the 糖心产精国品免费入口*完整版 of Mg-Al alloy are discussed. The advantages and disadvantages of the commonly used protective technology on the surface of Mg-Al alloy are reviewed.
中图分类号 TG146.2DOI 10.11973/fsyfh-201809001
所属栏目 专论
基金项目 国家重点研发计划（2016YFB0701201；2016YFB0701203；2017YFB1103701）；国家自然科学基金（51671101；51464034；51062003；11564025）；江西省自然科学基金（Nos.20172BCB22002；20171BCD40003；20161ACB21003；20162BCB23013）；江西省教育厅重点计划（GJJ150010）
收稿日期 2017/3/20
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引用该论文: WU Jin,LUO Lan,LIU Yong,XIONG Tinghui. Research Progress on Corrosion Resistance of Mg-Al Magnesium Alloy[J]. Corrosion & Protection, 2018, 39(9): 651
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参考文献
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【5】 刘长瑞,王伯建,胡裕邦. 镁合金材料在电子行业的开发应用前景[J]. 铝镁通讯,2001(2):53-55.
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【7】 李玉兰,刘江,彭晓东. 镁合金压铸件在汽车上的应用[J]. 特种铸造及有色合金,1999(1):120.
【8】 陈晓阳,曾大本. 镁合金铸件的应用现状及发展前景[J]. 铸造,1999(11):53-54.
【9】 刘正,王越,王中光,等. 镁基轻质材料的研究与应用[J]. 材料研究学报,2000,14(5):449-456.
【10】 LIU L J,SCHLESINGER M. Corrosion of magnesium and its alloys[J]. Corrosion Science,2009,51(8):1733-1737.
【11】 SHI Z,LIU M,ATRENS A. Measurement of the corrosion rate of magnesium alloys using tafel extrapolation[J]. Corrosion Science,2010,52(2):579-588.
【12】 BRADY M P,FAYEK M,ELSENTRIECY H H,et al. Tracer film growth study of hydrogen and oxygen from the corrosion of magnesium in water[J]. Journal of the Electrochemical Society,2014,161(9):C395-C404.
【13】 UNOCIC K A,ELSENTRIECY H H,BRADY M P,et al. Transmission electron microscopy study of aqueous film formation and evolution on magnesium alloys[J]. Journal of the Electrochemical Society,2014,161(6):C302-C311.
【14】 BRADY M P,ROTHER G,ANOVITZ L M,et al. Film breakdown and nano-porous Mg(OH)2 formation from corrosion of magnesium alloys in salt solutions[J]. Journal of the Electrochemical Society,2015,162(4):140-149.
【15】 HARA N,KOBAYASHI Y,KAGAYA D,et al. Formation and breakdown of surface films on magnesium and its alloys in aqueous solutions[J]. Corrosion Science,2007,49(1):166-175.
【16】 SONG G,BOWLES A L,STJOHN D H. Corrosion resistance of aged die cast magnesium alloy AZ91D[J]. Materials Science & Engineering A,2004,366(1):74-86.
【17】 SONG G,ATRENS A,WU X,et al. Corrosion behaviour of AZ21,AZ501 and AZ91 in sodium chloride[J]. Corrosion Science,1998,40(10):1769-1791.
【18】 WEI L Y,WESTENGEN H,AUNE T K,et al. Magnesium technology 2000[M]. Warrendale,Pa:TMS,2000:153.
【19】 LUNDER O,LEIN J E,AUNE T K,et al. The role of 糖心产精国品免费入口*完整版 phase in the corrosion of Mg alloy AZ91[J]. Corrosion,1989,45(9):741-748.
【20】 HERMANN F,SOMMER F,JONES H,et al. Corrosion inhibition in magnesium-aluminium-based alloys induced by rapid solidification processing[J]. Journal of Materials Science,1989,24(7):2369-2379.
【21】 ZENG R,ZHANG J,HUANG W,et al. Review of studies on corrosion of magnesium alloys[J]. Transactions of Nonferrous Metals Society of China,2006,16:763-771.
【22】 SINGH R R K. The role of microstructure in localized corrosion of magnesium alloys[J]. Metallurgical and Materials Transactions A,2004,35(8):2525-2531.
【23】 白力静,张华,袁颖,等. β-Mg17Al12相含量对AZ91镁合金腐蚀行为的影响[J]. 西安大理工学学报,2011,27(1):31-35.
【24】 SONG G L,ATRENS A. Corrosion mechanisms of magnesium alloys[J]. Advanced Engineering Materials,1999,1(1):11-33.
【25】 范晓明,万朋,文红艳. Mn含量对含铁AZ91D镁合金铸态组织与性能的影响[J]. 中国铸造装备与技术,2008(6):16-18.
【26】 陈先华,王敬丰,汤爱涛,等. 杂质元素对镁合金组织与性能的影响及其对应措施[J]. 材料导报,2010,24(3):37-41.
【27】 ESMAILY M,BLVCHER D B,SVENSSON J E,et al. New insights into the corrosion of magnesium alloys-the role of aluminum[J]. Scripta Materialia,2016,115:91-95.
【28】 高慧. 适用于镁合金的高效缓蚀剂的研究[D]. 重庆:西南大学,2011.
【29】 MÖ P,MM A. Magnesium alloying,some potentials for alloy development[J]. Journal of Japan Institute of Light Metals,1992,42(12):679-686.
【30】 GARBOGGINI A,MCSHANE H B. Effect of zinc and silicon additions on structure and properties of rapidly solidified Mg-Al alloys[J]. Materials Science and Technology,1994,10(9):763-770.
【31】 FENG H,LIU S,DU Y,et al. Effect of the second phases on corrosion behavior of the Mg-Al-Zn alloys[J]. Journal of Alloys and Compounds,2017,695:2330-2338.
【32】 MAKAR G L,KRUGER J. Corrosion studies of rapidly solidified magnesium alloys[J]. Journal of the Electrochemical Society,1990,137(2):414-421.
【33】 TSUCHIYA T,WATANABE K,MATSUDA K,et al. Effect of Al and Mn contents on microstructure in AM-series magnesium alloys[J]. Advanced Materials Research,2011,409:358-361.
【34】 薛俊峰. 镁合金防腐蚀技术[M]. 北京:化学工业出版社,2010.
【35】 张诗昌,段汉桥,蔡启舟,等. 主要合金元素对镁合金组织和性能的影响[J]. 铸造,2001,50(6):310-315.
【36】 MATSUBARA H,ICHIGE Y,FUJITA K,et al. Effect of impurity Fe on corrosion behavior of AM50 and AM60 magnesium alloys[J]. Corrosion Science,2013,66:203-210.
【37】 宋佩维. 往复挤压Mg-Al-Si合金的组织、性能及强化机制[D]. 西安:西安理工大学,2007.
【38】 LI G Q,WU G H,FAN Y,et al. Effect of the main alloying elements on microstructure and 糖心产精国品免费入口*完整版 of magnesium alloys[J]. Zhuzao Jishu (Foundry Technology),2006,27(1):79-83.
【39】 LUNDER O,NISANCIOGLU K,HANSEN R S. Corrosion of die cast magnesium-aluminum alloys[R]. SAE Technical Paper,1993.
【40】 HILLIS J E,SHOOK S O. Composition and performance of an improved magnesium AS41 alloy[R]. SAE Technical Paper,1989.
【41】 WEI L Y. Development of microstructure in cast magnesium alloys[D]. Goteborg:Chalmers University of Technology,1990.
【42】 张芳君. 合金化元素对镁合金糖心产精国品免费入口*完整版能的影响[D]. 重庆:重庆大学,2012.
【43】 王喜峰,齐公台. 混合稀土对AZ91镁合金在NaCl溶液中腐蚀行为的影响[J]. 材料开发与应用,2002,17(5):34-36.
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